@Joseph Hawkins yeah your instinct is actually pretty solid here. At extreme range the link margin is thin enough that the receiver is working hard to pull packets out of the noise floor, and if you're hammering the advertising channels with a short interval you're not giving the radio time to recover between transmissions — plus you're increasing the probability that two adv packets land on the same channel at the same time as interference from other sources. The STM32WB07 on the MultiNav Pro+ has pretty aggressive LNA sensitivity so it helps, but you can't hardware your way out of a collision on ch37/38/39 if the timing is just unlucky.
What I'd actually suggest is running a longer interval — somewhere in the 500ms–1s range — and compensating by extending the scan window on the central side so it's listening long enough to catch an adv event even with that slower cadence. You get the power savings on the peripheral, you reduce the collision window, and at that range the few hundred milliseconds extra to first discovery doesn't really matter in a sensor deployment context anyway. The solar buffer situation makes this even clearer — if your harvesting is marginal, radio TX is probably your biggest draw and tightening that interval is the worst place to fight it.
One thing worth checking: if you're using the AI Firmware Builder in the Dev Hub, you can describe this exact scenario (low-power peripheral, long-range central, solar buffer) and it'll generate a tuned config that balances the advertising timing with sleep cycles in between. Saves a lot of empirical tuning time.