@Linda Lopez yeah this is a solid use case for the MultiNav Pro+ and it does work in a headless peer-to-peer setup — the module can handle the connection management autonomously once it's configured, so you don't need an active host MCU babysitting the link on either end. The AT command config to set central/peripheral roles is the right starting point, and once that's saved to flash it persists across power cycles which matters a lot for remote deployments.
The one thing I'd flag is that your sensor data flow architecture matters here — if module B is just receiving and logging, that's straightforward, but if you need it to do anything meaningful with the data it's still going to need something on that end to process it, even if it's just a small microcontroller. The BLE module itself is handling the RF link autonomously, not the application logic on top of it.
I'd also recommend jumping into the Dev Hub and checking the AI Firmware Builder if you haven't already — describe your exact deployment topology (sensor node, data sink, polling interval, whatever) and it'll generate firmware that handles the connection setup and data flow cleanly, which is a lot faster than piecing it together from the AT command docs alone.